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022 _a09733574
040 _aMAIN
041 _aEnglish
100 _aChiou, Paul
_963403
245 _aSource Identification of Houston Aerosol with Carbon Fractions in Positive Matrix Factorization /
_cPaul Chiou...et.al.
310 _a7 Vol., Issue 1-2 (135-152 p.)
520 _aSpeciated samples of PM,, were collected at the Deer Park site in Houston, Texas by US EPA (Environmental Protection Agency) from July of 2004 to December of 2007. A total of 307 (Envirorwich 55 species including 4 organic carbon fractions were measured however were excluded because of too many below-detection-limit data. The data set was analyzed by positive matrix factorization (PMF) to infer the sources of PM observed at the site. The analysis identified ten source-related factors: sulfate-rich secondary aerosol (53.3%), highway traffic (13.7%), aged sea-salt (7.5%), airborne soil (5.4%), nitrate-rich secondary aerosol (5.3%) gasoline vehicle (5.3%), wood smoke (3.4%), railroad traffic (3.1%), sea salt (1.7%), and on- road diesel emissions (1.2%). Sulfate and nitrate mainly exist as ammonium salts. The sulfate- rich secondary aerosol accounts for the highest of the PM, mass concentration at the site. The factor containing highest concentrations of Cl and Na was attributed to sea salt due to the proximity of the monitoring sites to the Gulf of Mexico. The aged sea-salt was related to the sea salt aerosol but was separately identified because of the chlorine replacement reactions. Furthermore, unlike some previous studies (Chiou et al. 2008, 2009) using only the traditional OC data, this study demonstrates that the utilization of fractional carbon data can enhance source apportionment to separate diesel emissions from gasoline vehicle sources.
650 _aAirborne Pariculate Matter
_963405
650 _aCarbon Fraction
_963408
650 _aPositive Matrix Factorization
_963410
650 _aConditional Probability Function
_963412
700 _aShah, Jalpa
_4Co- Author
_963414
700 _aLin, Che- Jen
_4Co- Author
_963416
700 _aTadmor, Rafael Tadmor
_4Co- Author
_963418
700 _aChu, Hsing- Wei
_4Co- Author
_963420
700 _aT.C. Ho
_4Co- Author
_963422
773 0 _08774
_912505
_dNew Delhi : Serials Publications, 2004.
_oJ000078
_tInternational Journal of Environment & Development
_x09733574
942 _cART
999 _c15347
_d15348